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Advisory Committee member Kevin Zacharoff, an anesthesiologist, and clinical assistant professor at the Renaissance School of School of Medicine at Stony Brook University, explained his vote against the substance

Notably, during models CASSCF(14, 13) geometric optimization, the HOMO and LUMO molecular orbitals drew our attention from the beginning (Figs S1-S3, in Supporting Information (SI))

Starting at the lower end and staying consistent is generally the most sensible approach