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doi: 10.1002/1097-0339(200007)23:1 3.0.CO;2-B 22 KuchelmeisterKLotzCSchnmayrRSchachenmayrW

This nocturnal "maintenance window" is when your cells regenerate, your brain flushes out metabolic waste, and your tissues repair the wear and tear of a day spent adventuring

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The article's table says freezing below zero degrees Celsius alters pH and crystal structure and may cause precipitation or separation